Chem. Soc. Rev., 2025, Advance ArticleDOI: 10.1039/D4CS00429A, Review ArticleIsabelle Martinier, Léa Trichet, Francisco M. FernandesWe propose a simplified two-layered model of native tubular tissues, based on the composition and structure. This approa…
Israel Journal of Chemistry, EarlyView.
A simple, quick, and cost-effective protocol is presented herein for the sustainable synthesis of 2-(N-arylamino)benzothiazoles from 2-haloanilines and arylisothiocyanates by using an ionic liquid supported heterogeneous Cu(II) catalyst derived from N-methylimidazole. Compared to the use of homogeneous catalysts and additives, which require long reaction times and high reaction temperatures, this methodology has a broad substrate scope and proceeds in short reaction times to afford compounds in excellent yields under microwave irradiation. In addition, the catalyst can be extracted easily and is recyclable up to five times with no significant loss in catalytic activity.
An indium-catalyzed cyanomethylation of α-alkynyl α,β-unsaturated ketones with 3-azido-2-methylbut-3-en-2-ol is presented. Furan-substituted propanenitriles were produced in yields of 29–97%. The reaction involves a nucleophile addition/cycloisomerization process.