The Size Induced Phase Transition in the Rb0.95NbxMo2−xO6.475–0.5x (x=1.31–1.663) Solid Solution with β‐Pyrochlore Structure
European Journal of Inorganic Chemistry, EarlyView.
European Journal of Inorganic Chemistry, EarlyView.
ChemMedChem, Volume 18, Issue 22, November 16, 2023.
ChemSystemsChem, Volume 5, Issue 6, November 2023.
ChemSystemsChem, Volume 5, Issue 6, November 2023.
Synlett 2023; 34: V-DOI: 10.1055/s-0042-1751622Georg Thieme Verlag KG Rüdigerstraße 14, 70469 Stuttgart, GermanyArticle in Thieme eJournals:Table of contents
Asymmetric cyanosilylation serves as an important tool to convert easily available ketones into cyanohydrins of diverse reactivity. Whereas a large library of organocatalysts and transition-metal catalysts have been identified for monoketones, cyanosilylation of more-complex substrates, particularly those giving enantioenriched vicinal stereocenters, is underexplored in comparison. Here, a pair of recently published kinetic resolution and desymmetrization methods are highlighted for their success in constructing complex vicinal stereocenters by cyanosilylation using tailored aluminum and magnesium catalysts, respectively.1 Introduction2 Kinetic Resolution of α-Branched Ketones3 Desymmetrization of 1,3-Diketones4 Conclusion
Volume 44, Issue 5-6, November 2023, Page 361-380.