General protocols for the N-functionalization of 1,2-azaborines with C(sp3), C(sp2), or C(sp) electrophiles are described. The syntheses of a new parental BN isostere of trans-stilbene and a BN isostere of a lisdexamfetamine derivative were accomplished with the developed methodology.
European Journal of Inorganic Chemistry, Volume 26, Issue 30, October 24, 2023.
ChemPhotoChem, Volume 7, Issue 9, September 2023.
Journal of Heterocyclic Chemistry, Volume 60, Issue 10, Page 1768-1777, October 2023.
Chemistry – A European Journal, EarlyView.
Sulfoximines as S-aryl surrogates permit the preparation of 3-arylsulfenylindoles through reaction with indoles in the presence of I2 under visible-light irradiation. This environmentally friendly approach is fast, mild, metal-, photocatalyst-, additive-, and oxidant-free, and it provides the desired products in moderate to good yields with a wide substrate scope.
Chinese Journal of Chemistry, Volume 41, Issue 23, Page 3484-3492, 1 December 2023.