August 2022

A bimetallic Pd/Cu catalyst supported on a metal-organic-framework-derived cobalt oxide was prepared and characterized by SEM, EDS, XRD, XPS, and ICP-OES analyses. The catalyst promoted the Sonogashira reaction of aryl iodides with terminal alkynes at a low loading of the palladium (0.032 mol%) and copper species (0.012 mol%) to give the corresponding disubstituted alkynes in moderate to good yields. When the catalyst was recovered by using an external magnetic field, its catalytic activity decreased slightly in a second cycle.

First time, Pd-Rice Husk Ash (Pd/RHA) and Pd-Banana Peel Ash (Pd-BPA) were used as eco-friendly catalysts in the C–S cross-coupling reaction of 5-bromo-2,1,3-benzothiadiazole with various benzene thiols in DMF under microwave irradiation at 75 °C, 200 W (100 psi) for 15–25 min. These catalysts were produced from agro-industrial wastes, such as rice husk ash and banana peel ash. These can be recycled and reused up to five catalytic cycles without loss of catalytic efficiency.