European Journal of Organic Chemistry
Synthesis of Benzothiazinones from Benzoyl Thiocarbamates: Application to Clinical Candidates for Tuberculosis Treatment
European Journal of Organic Chemistry, Accepted Article.
European Journal of Organic Chemistry
Rh(III)‐Catalyzed N‐Arylation of Alkyl Dioxazolones with Arylboronic Acids for the Synthesis of N‐Aryl Amides
European Journal of Organic Chemistry, Accepted Article.
European Journal of Organic Chemistry
Hypervalent Iodine‐Mediated Azidation Reactions
European Journal of Organic Chemistry, Accepted Article.
ChemElectroChem
Electrochemically Accessing ROS‐Related Cytotoxicity through the Oxygen Reduction Reaction to Identify Antimicrobial Agents
ChemElectroChem, Accepted Article.
Chemistry – A European Journal
Fe‐Catalyzed Amidation of Allylic Alcohols by Borrowing Hydrogen Catalysis
Chemistry – A European Journal, EarlyView.
Synlett
Advances in the Iron-Catalyzed Direct Functionalizations of Heterocycles
Direct functionalization of heterocycles is an advanced strategy for diversifying privileged and biorelevant heterocycle-containing molecules. Particularly, use of the most abundant transition metal, iron, as a catalyst makes this process highly cost-effective and sustainable. Recently, some progress has been realized towards the direct functionalization of heterocycles under iron catalysis. Herein, we present the developments in the C–H bond functionalizations and related reactions of various heterocycles by abundant iron salts. This Synpacts is categorized into different sections based on heterocycles being functionalized, and each section is discussed based on the type of reaction catalyzed by iron.1 Introduction2 Functionalization of Indoles2.1 Alkylation2.2 Alkenylation2.3 Other Reactions3 Oxindoles and Isatins3.1 C–C Bond Formation3.2 C–Heteroatom Bond Formation4 Pyridines and Furans5 Functionalization of Azoles6 Summary and Outlook
Synlett
Palladium-Catalyzed Stereospecific Coupling of BINOL-bistriflates and Zinc Cyanide and Applications in the Synthesis of 1,1′-Binaphthyl-2,2′-bisoxazolines (BOXAX)
A palladium-catalyzed synthesis of enantiopure [1,1′-binaphthalene]-2,2′-dicarbonitriles from BINOL-bistriflates and zinc cyanide is reported. This cross-coupling reaction employs a 0.1–5 mol% catalyst loading, and is scalable and stereospecific. The synthetic applications of this reaction are demonstrated by product derivatizations and the synthesis of [1,1′-binaphthalene]-2,2′-bisoxazolines (BOXAX).
Synlett
Synthetic Studies toward Australifungin
As a fungal metabolite, australifungin possesses an α-diketone and a β-ketoaldehyde moiety on its trans-decalin backbone. Microwave-assisted intramolecular Diels–Alder reaction was used as a key strategy to establish the trans-decalin moiety. Further functionalization of the ring B side chain installed the β-ketoaldehyde, one of the two unique functional groups along with the α-diketone.