Journal of Physical Organic Chemistry
My first publication
Journal of Physical Organic Chemistry, Volume 35, Issue 11, November 2022.
ChemMedChem
Successful Drug Discovery, Volume 5. Edited by János Fischer, Christian Klein, and Wayne E. Childers
ChemMedChem, Volume 17, Issue 9, May 4, 2022.
ChemMedChem
Solid State Development and Processing of Pharmaceutical Molecules: Salts, Cocrystals, and Polymorphism. Edited by Michael Gruss
ChemMedChem, Volume 17, Issue 9, May 4, 2022.
Applied Organometallic Chemistry
Post‐assembly modification of discrete poly‐NHC‐derived organometallic assemblies
Applied Organometallic Chemistry, Volume 38, Issue 10, October 2024.
Uncategorized
Asymmetric Rhodium-Catalyzed Allylic Substitution Reactions with Nitrile-Stabilized Carbanions
This Account summarizes our recent work on rhodium-catalyzed allylic alkylation reactions with nitrile-stabilized carbanions. Despite the challenges associated with employing nitrile-stabilized nucleophiles in transition-metal-catalyzed reactions, we have developed enantiospecific and enantioselective allylic alkylation reactions. Notably, these novel reactions permit expedient and selective access to an array of acyclic ternary and quaternary stereogenic centers present in important biologically active and functional molecules.1 Introduction2 Enantiospecific Allylic Alkylation Reactions with Nitrile-Stabilized Anions3 Enantioselective Allylic Alkylation Reactions with Nitrile-Stabilized Anions4 Conclusion